As one of the many new faces of the brand, she is certainly in interesting company: former communist leader Mikhail Gorbachev and French actress Catherine Denueve have also appeared in separate advertisements for the company.
She added her famous air of old Hollywood glamour to the new shoot, in which she shows off her alabaster skin and much-envied curves in a series of provocative poses.
Siren: Scarlett strikes a seductive pose for a new ad campaign
Knees up: the actress looked red hot in her latest shoot
The 22-year-old, who has been linked to Justin Timberlake and actor Ryan Reynolds in recent times, says she has embraced her voluptuous look.
She said: "I think that everybody has days that they feel more accepting of their own body than other days. I wouldn't say it's something I struggle with. I have what I have and I try and appreciate that."
Still, there are no plans to take up a more revealing role.
In the bag: the 22-year-old, who is also the face of L'Oreal, is now in strong demand
Orange crush: she may look uncomfortable, but she still looks gorgeous
The actress has denied recent reports she is set to star as a porn star in a film version of Jenna Jameson's autobiography.
While Jameson has voiced her hopes that actress would sign on for the role, Johansson doesn't share her enthusiasm.
The star's spokesperson told People magazine: "Scarlett has never seen a script nor been approached about this project. She also has no interest in playing this role."
Well heeled: the actress clearly gets her kicks out of designer labels
Johansson is currently filming a new movie with Woody Allen in Barcelona.
The film, her third by the Oscar-winning director, will also star Spanish actress Penelope Cruz and heartthrob Javier Bardem.
She is expected to be in Spain for seven weeks in total, including one week in the northern Spanish region of Asturias, before returning to New York.
Unlikely bedfellow: Scarlett has joined Mikhail Gorbachev as one of the new faces of the brand
French twist: Catherine Denueve poses on Vuitton trunks
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